Chemistry Letters p. 1141 - 1144 (1988)
Update date:2022-07-29
Topics:
Koga, Teruyoshi
Makinouchi, Shinako
Okukado, Nobuhisa
Acyliron complexes, easily prepared from disodium tetracarbonylferrate and alkyl halides, reacted with aryl iodides in the presence of a catalytic amount of Pd(PPh3)4 and a cocatalyst, ZnCl2, to give aromatic ketones in good yields. (R)-2-Methyl-1-phenyl-octanone was prepared starting from (S)-2-bromooctane in an excellent optical yield.
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