Ytterbium Metal-promoted Novel Cross-coupling Reaction between Diaryl Ketones and Electrophiles

DOI: 10.1039/c39880000668

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 668 - 670 (1988)

Update date:2022-08-02

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Authors:

Hou, Zhaomin

Takamine, Kan

Aoki, Osamu

Shiraishi, Hiroyuki

Fujiwara, Yuzo

Taniguchi, Hiroshi

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Article abstract of DOI:10.1039/c39880000668

In the presence of Yb metal, diaryl ketones react nucleophilically with octan-2-one, acetonitrile, epoxides, and CO2 to give the corresponding unsymmetrical pinacols, α-hydroxy ketones, 1,3-diols, and α-hydroxy carboxylic acids, respectively.

Full text of DOI:10.1039/c39880000668

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