Ytterbium Metal-promoted Novel Cross-coupling Reaction between Diaryl Ketones and Electrophiles

DOI: 10.1039/c39880000668

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 668 - 670 (1988)

Update date:2022-08-02

Topics:

Authors:

Hou, Zhaomin

Takamine, Kan

Aoki, Osamu

Shiraishi, Hiroyuki

Fujiwara, Yuzo

Taniguchi, Hiroshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39880000668

In the presence of Yb metal, diaryl ketones react nucleophilically with octan-2-one, acetonitrile, epoxides, and CO2 to give the corresponding unsymmetrical pinacols, α-hydroxy ketones, 1,3-diols, and α-hydroxy carboxylic acids, respectively.

Full text of DOI:10.1039/c39880000668

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2-(9-hydroxy-9-fluorenyl)cyclohexanol

Cas No:116672-43-6

R&D Labs maybe for 116672-43-6

Zhejiang PRIMAR Import & Export Trade Co., Ltd.

Contact:86-570-3630818

Address:No.1Puzhuyuan,Quhua,Zhejiang Province,China324004
ZCIC INTERNATIONAL LTD

Contact:+86-512-56795332

Address:No227 Shuanglong Rd, Fenghuang, Zhangjiagang
Jiaozuo Zhongwen Trading Coporation Limited

Contact:+86 0391-3553810

Address:East Renmin Road
Ningbo Bichem Pharmaceutical Co.,Ltd

Contact:18957868060 057487816388

Address:ningbo
Fujian Huitian Biological Pharmacy Co., Ltd.

Contact:0086-598-8300831; 8339920

Address:No.46,Taijiang Road,Sanming City,Fujian,China

Relevant to this article

Synthesis of the C16-C23 effector domain of FK-506 via copper-catalysed metallate rearrangement of an α-alkoxyalkenylcuprate

Doi:10.1055/s-1995-3871
(1995)
NUCLEOPHILIC SUBSTITUTION AT A SATURATED CARBON ATOM WITH RETENTION OF CONFIGURATION: THE REACTION OF TRANS-2-HALO-3-TERT-BUTYLOXIRANES WITH PHENOLATES

Doi:10.1016/S0040-4039(00)98728-8
(1985)
On-site modification of oligopeptides: Conversion of seryl into (exo)-2-azabicyclo[2.2.1]hept-5-ene-3-carbonyl residues

Doi:10.1016/0040-4039(94)02432-B
(1995)
A rhodium IBiox[(-)-menthyl] complex as a highly selective catalyst for the asymmetric hydroarylation of azabicyles: An alternative route to epibatidine

Doi:10.1021/ol101067d
(2010)
Novel uric acid-based nano organocatalyst with phosphorous acid tags: Application for synthesis of new biologically-interest pyridines with indole moieties via a cooperative vinylogous anomeric based oxidation

Doi:10.1016/j.mcat.2021.111549
(2021)
Structural and spectroscopic studies of new o-, m- and p-nitrobenzyl esters of lasalocid acid

Doi:10.1016/j.molstruc.2007.07.020
(2008)

Article Doi