Tetrahedron Letters p. 4337 - 4340 (1985)
Update date:2022-08-02
Topics:
Gasteiger, Johann
Kaufmann, Karlheinz
Herzig, Christian
Bentley, T. William
Whereas reaction of trans-2-chloro or 2-bromo-3-tert-butyloxirane with thiophenolate occurs at C-3 to give 2-phenylmercapto-3,3-dimethylbutanal, phenolates give substitution at C-2 with retention of the oxirane ring and retention of configuration with kin
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