1,4-Dioxene in Organic Synthesis. 6. Substituted 2-Vinyl-1,4-dioxenes: Useful Intermediates for the Synthesis of Highly Functionalized Compounds

DOI: 10.1021/jo00259a012

Source and publish data:

Journal of Organic Chemistry p. 5672 - 5679 (1988)

Update date:2022-07-29

Topics: Organic synthesis Substituted

Authors:

Fetizon, Marcel

Goulaouic, Pierre

Hanna, Issam

Prange, Thierry

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Article abstract of DOI:10.1021/jo00259a012

Substituted 2-vinyl-1,4-dioxenes 3, prepared by dehydration of allylic alcohols 2 with MsCl-Et3N or SOCl2-Py, undergo a <4 + 2> cycloaddition reaction with various dienophiles.Exposure of 4, obtained by Diels-Alder reaction with dimethyl acetylenedicarbox

Full text of DOI:10.1021/jo00259a012

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