Tetrahedron Letters p. 6155 - 6158 (1987)
Update date:2022-08-05
Topics:
Kaupp, Gerd
Ringer, Ernst
(2-Methyl)indolizine upon photoexcitation is trapped by stilbenes with fluorescence quenching and gives regio- and stereoselectively only the 1:1 adducts 3 (6) and the 1:2-adduct 4 in good yields.The surprising results are rationalized in terms of the well-documented diradical mechanism and quantum chemical data.
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