Journal of the Chemical Society. Chemical communications p. 605 - 606 (1988)
Update date:2022-08-02
Topics:
Ogawa, Seiichiro
Shibata, Yasushi
The first complete synthesis of acarbose (1a), the pseudotetrasaccharidic α-amylase inhibitor, is reported: coupling of the protected (+)-valienamine (16) and the epoxide (9) derived from 1'',6''-anhydromaltotriose (3), followed by deprotection; likewise, adiposin-2 (2a), the 6'-hydroxy analogue of (1a), has also been synthesised.
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