Kinetic resolution of racemic 1 -alkyl-2-methylenecyclopropanes via palladium-catalyzed silaborative C-C cleavage

DOI: 10.1021/ol900829c

Source and publish data:

Organic Letters p. 2880 - 2883 (2009)

Update date:2022-08-04

Topics:

Authors:

Ohmura, Toshimichi

Taniguchi, Hiroki

Suginome, Michinori

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Article abstract of DOI:10.1021/ol900829c

Kinetic resolution of racemic 1-alkyl-2-methylenecyclopropanes via silaborative C-C cleavage was efficiently catalyzed by a palladium complex bearing a chiral phosphoramidite, affording 2-boryl-3-silylmathy 1-1 -alkenes as major products with up to 92% ee

Full text of DOI:10.1021/ol900829c

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