Journal of Organic Chemistry p. 5586 - 5588 (1988)
Update date:2022-07-31
Topics:
Koreeda, Masato
Ricca, Daniel J.
Luengo, Juan I.
The synthesis of the verrucarol skeleton 3 has been achieved in a highly efficient and diastereoselective manner through the intramolecular Diels-Alder reaction of the cyclopentyl C-ring-tethered diene-dienophile 7.Remarkably, this intramolecular Diels-Alder reaction proceeds readily at room temperature under catalysis by neutral alumina.
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