Synthesis and properties of a silyl(silylene)ruthenium complex: activation barrier of the Ru=Si bond rotation and facile replacement of the methyl groups with alkoxy groups of a silyl ligand

DOI: 10.1021/om900177z

Source and publish data:

Organometallics p. 3963 - 3965 (2009)

Update date:2022-09-26

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Authors:

Hashimoto, Hisako

Sato, Jun

Tobita, Hiromi

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Article abstract of DOI:10.1021/om900177z

A silyl(silylene)ruthenium complex, Cp* Ru(CO)(=SiMes ₂)SiMe₃ (2), was synthesized by the reaction of Cp*Ru(CO) (py)Me with HSiMe₂SiMeS₂Me (Mes = 2,4,6trimethylphenyl). In contrast to its iron analogue Cp*Fe(CO)

Full text of DOI:10.1021/om900177z

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