Synthesis of PdII complexes bearing an enantiomerically resolved seven-membered N-heterocyclic carbene ligand and initial studies of their use in asymmetric Wacker-type oxidative cyclization reactions

DOI: 10.1016/j.tet.2009.04.072

Source and publish data:

Tetrahedron p. 5084 - 5092 (2009)

Update date:2022-08-04

Topics:

Authors:

Scarborough, Christopher C.

Bergant, Ana

Sazama, Graham T.

Guzei, Ilia A.

Spencer, Lara C.

Stahl, Shannon S.

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Article abstract of DOI:10.1016/j.tet.2009.04.072

The development of enantiomerically resolved, axially-chiral seven-membered N-heterocyclic carbene (⁷NHC) ligands for palladium is described. These ⁷NHC ligands are derived from enatiomerically pure 2,2′-diamino-6,6′-dimethylbiphenyl

Full text of DOI:10.1016/j.tet.2009.04.072

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