FORMATION OF ACCEPTOR SUBSTITUTED PHENYLNITRENES VIA α-ELIMINATION UNDER MILD CONDITIONS

DOI: 10.1016/S0040-4039(00)82042-0

Source and publish data:

Tetrahedron Letters p. 1781 - 1784 (1988)

Update date:2022-07-29

Topics:

Authors:

Bosold, Ferdinand

Boche, Gernot

Kleemiss, Wolfgang

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)82042-0

The acceptor substituted 1a-d and 2d react with n-butylamine to give 5, 6 and 7.This strongly suggests the intermediate formation of substituted phenylnitrenes via α-elimination.

Full text of DOI:10.1016/S0040-4039(00)82042-0

Products guided by the article

Product name:7-Butylamino-6H-azepine-4-carbonitrile

Cas No:117911-69-0

R&D Labs maybe for 117911-69-0

SINO GREAT ENTERPRISE LTD.

Contact:+86-731-84427351

Address:154 JIANXIANG SOUTH ROAD
Hebei DaPeng Pharm & Chem Co., Ltd.

Contact:86-317-7298678,0576-88861898 88861908

Address:West Songmen Village, East Songmen Town, Wuqiao, Cangzhou, Hebei ,China
NANCHANG QINZHI SCI&TEC.CO.,LTD(expird)

Contact:+86-13687004106

Address:Hero South Road,Hero Zone,Nanchang,Jiangxi,China
Zhejiang Quzhou Zhengbang Organosilicon Co.,ltd.

Contact:86-570-3375195

Address:No.17 Lingqing Road technology industry,Quzhou City,Zhejiang Province,China
Dongguan Albiya Energy Science and Technology Co.,Ltd

Contact:+86-769-22181286

Address:Huanan Industial Park, Dongguan,China

Relevant to this article

A facile access to a novel bidentate enantiomerically pure P,N-donor ligand

Doi:10.1039/b822144h
(2009)
Direct synthesis of (PhSe)₄Ge and (PhTe)₄Ge from activated hydrogenated germanium - Crystal structure and twinning of (PhTe)₄Ge

Doi:10.1002/ejic.200390183
(2003)
Selective intramolecular palladium(II)-catalyzed aminooxygenation vs. diamination of alkenylureas: Efficient microwave-assisted reactions to bicyclic piperazinones

Doi:10.1002/adsc.201300104
(2013)
Synthesis of glucoside-based imidazolium salts for Pd-catalyzed cross-coupling reaction in water

Doi:10.1016/j.carres.2020.108079
(2020)
Synthesis of 6-deoxy-6-fluorosucrose, and its inhibition of Leuconostoc and Streptococcus D-glucansucrases.

Doi:10.1016/0008-6215(88)85061-4
(1988)
Zn(II)-catalyzed synthesis of piperidines from propargyl amines and cyclopropanes

Doi:10.1021/ol901435k
(2009)

Article Doi