Synthesis of terminal trimethylsilyl enynes via a sililated arsonium ylide

DOI: 10.1016/0022-328X(88)80114-1

Source and publish data:

Journal of Organometallic Chemistry p. 181 - 184 (1988)

Update date:2022-08-05

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Authors:

Shen, Yanchang

Liao, Quimu

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Article abstract of DOI:10.1016/0022-328X(88)80114-1

The reaction of 3-(trimethylsilyl)-2-propynylidenetriphenylarsorane, generated in situ from the corresponding arsonium salt and n-butyllithium, with ketones gave terminal trimethylsilyl enynes in 72-100 percent yields.These stereochemical study revealed t

Full text of DOI:10.1016/0022-328X(88)80114-1

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Product name:Arsonium, triphenyl[3-(trimethylsilyl)-2-propynyl]-, bromide

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