CHIRAL THIOPHENE DIOXIDES AND THIOPHENE S,N-YLIDES AS DIENES FOR ASYMMETRIC DIELS-ALDER APPLICATION

DOI: 10.1016/S0040-4020(01)85944-5

Source and publish data:

Tetrahedron p. 3127 - 3138 (1988)

Update date:2022-08-05

Topics:

Authors:

Dillen, Jan L.M.

Meth-Cohn, Otto

Moore, Clive

van Rooyen, Petrus H.

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Article abstract of DOI:10.1016/S0040-4020(01)85944-5

2-Menthyltrihalothiophene S,S-dioxides are efficient asymmetric dienes in Diels-Alder reactions with dienophiles to give regio- and stereoisomerically pure adducts.Thus styrene, allyl alcohol, methyl acrylate and acrylamide give solely one adduct while fl

Full text of DOI:10.1016/S0040-4020(01)85944-5

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