PHOTOCHEMICAL ACTIVATION OF ALUMINUM-ALKYL BOND IN ALUMINUM PORPHYRIN. CONJUGATE ADDITION REACTION WITH VINYL KETONE

DOI: 10.1246/cl.1985.1377

Source and publish data:

Chemistry Letters p. 1377 - 1380 (1985)

Update date:2022-08-03

Topics:

Authors:

Murayama, Hideki

Inoue, Shohei

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Article abstract of DOI:10.1246/cl.1985.1377

Tetraphenylporphinatoaluminum ethyl undergoes addition reaction toward vinyl ketone via a novel enolate aluminum porphyrin as the intermediate.This reaction is remarkably accelereted upon irradiation with visible light retaining the reaction mode.

Full text of DOI:10.1246/cl.1985.1377

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