PALLADIUM(0)-CATALYZED HYDROXYLAMINATION OF ALLYL ESTERS. SYNTHESIS OF N-ALLYLHYDROXYLAMINES AND SECONDARY ALLYLAMINES

DOI: 10.1016/0040-4039(88)85061-5

Source and publish data:

Tetrahedron Letters p. 2973 - 2976 (1988)

Update date:2022-07-29

Topics:

Authors:

Murahashi, Shun-Ichi

Imada, Yasushi

Taniguchi, Yuki

Kodera, Yoichi

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Article abstract of DOI:10.1016/0040-4039(88)85061-5

Palladium-catalyzed reaction of allyl esters with hydroxylamines gives N-allylhydroxylamines, which are readily converted into secondary allylamines upon treatment with zinc powder in a dilute HCl solution.

Full text of DOI:10.1016/0040-4039(88)85061-5

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Product name:N-Methyl-N-((E)-1-methyl-3-phenyl-allyl)-hydroxylamine

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