Journal of the Chemical Society. Chemical communications p. 270 - 272 (1988)
Update date:2022-08-04
Topics:
Bartra, Marti
Bou, Valenti
Garcia, Jordi
Urpi, Felix
Vilarrasa, Jaume
A new method is reported for the conversion of azido acids into lactams, via thioester formation and in situ azide reduction and cyclisation under high-dilution conditions; since the quantitative conversion of macrolactams to macrolactones has been shown to be feasible, this results in an indirect, alternative macrolactonisation procedure.
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