Synthetic Communications p. 1795 - 1802 (2014)
Update date:2022-09-26
Topics:
Singh, Shyam Babu
Verma, Pankaj Kumar
Tiwari, Kamleshwar
Singh, Mandavi
Ankit, Preyas
Fatma, Shahin
Singh, Jagdamba
Tiwari, Kamla Prasad
An efficient triphenylphosphine-catalyzed synthesis of β-acetamido carbonyls via multicomponent reaction of aromatic aldehydes, enolizable ketones or β-keto esters, acid chlorides and acetonitrile at room temperature is described. The process is remarkably simple, environmentally benign, and uses Lewis base for the first time in such type of reaction.
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