Tetrahedron Letters p. 3997 - 4000 (1988)
Update date:2022-09-26
Topics:
Manfredini, S.
Simoni, D.
Zanirato, V.
Casolari, A.
Ethyl 2,4-dioxoalkanoates react chemoselectively with pyrrolidine acetate at the more electrophilic C-2 carbonyl, producing enaminone esters which on reduction with NaCNBH3 followed by pyrrolidine elimination, were transformed into γ-oxo-acrylates.
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