Journal of the Chemical Society. Chemical communications p. 838 - 839 (1988)
Update date:2022-09-26
Topics: nucleophiles Stereoselective Ring Opening Reaction Experimental
Machiguchi, Takahisa
Hasegawa, Toshio
Ohno, Megumi
Kitahara, Yoshio
Funamizu, Makoto
Nozoe, Tetsuo
The tosylate (1) of tropone oxime undergoes a novel ring-opening reaction under mild conditions with secondary amines, alkoxides, and Grignard reagents affording stereoselectively 6-substituted (1Z,3Z,5Z)-hexa-1,3,5-triene-carbonitriles (2a-h) as sole pro
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