Journal of Organic Chemistry p. 1092 - 1097 (1989)
Update date:2022-07-31
Topics:
Glass, Richard S.
Farooqui, Firdous
Sabahi, Mahmood
Ehler, Kenneth W.
Reaction of α-toluenethiol with Ebselen oxide, 2, affords dibenzyl disulfide and seleno sulfide 5, R = PhCH2.In the course of this reaction, thiobenzaldehyde is formed and can be trapped with cyclopentadiene in 90percent yield.Reaction of 2-propene-1-thiol with 2 afforded thioacrolein dimer in 69percent yield and seleno sulfide 5, R = CH2-CH=CH2.Trapping, stereochemical, and isotopic exchange studies were used to determine if in the reaction of 2 with 1-heptanethiol, cyclohexanethiol, and N-acetyl-D,L-cysteine thiocarbonyl compounds heptanethial, cyclohexanethione, and 2-acetamino-3-thioxopropanoic acid (α-thioformyl-N-acetylglycine), respectively, are also formed.These studies showed that free thiocarbonyl compounds are not formed in these reactions.
View MoreContact:86-21 60347964
Address:No.1304, West Meilong Road, Minhang District, Shanghai, China
Zibo Xiaoguang Chemical Material Co., Ltd
Contact:15954099116
Address:Boshan Development Zone
jiangsu senxuan pharmaceutical and chemical co.,ltd
Contact:86-523-87982810
Address:hongqiao industrial zone,taixing,jiangsu china
Contact:+86-519-86339586，13584329896
Address:Changzhou Scientific and Education Park
Contact:0086-29-88315623
Address:S711, Innovation Bldg No.25 Gaoxin 1st Rd, Xian P.R of China 710075
Doi:10.1021/acs.inorgchem.8b01432
(2018)Doi:10.1016/j.bmcl.2015.01.047
(2015)Doi:10.1246/cl.1988.1291
(1988)Doi:10.1002/ejoc.200900462
(2009)Doi:10.1016/j.bmcl.2009.05.100
(2009)Doi:10.1016/j.bmcl.2009.07.056
(2009)
