RHODIUM(I)-CATALYZED ISOMERIZATION OF SILOXYCYCLOPROPANES LEADING TO ENOL SILYL ETHERS AND ALLYL SILYL ETHERS

DOI: 10.1016/S0040-4039(01)93380-5

Source and publish data:

Tetrahedron Letters p. 6887 - 6890 (1989)

Update date:2022-09-26

Topics:

Authors:

Ikura, Kiyoshi

Ryu, Ilhyong

Ogawa, Akiya

Kambe, Nobuaki

Sonoda, Noboru

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Article abstract of DOI:10.1016/S0040-4039(01)93380-5

The isomerization of siloxycyclopropanes to enol silyl ethers and allyl silyl ethers was accomplished by using 2 as a catalyst.Regiochemistry with respect to the newly formed double bond of the product was highly dependent on the substitution pattern of cyclopropane ring.

Full text of DOI:10.1016/S0040-4039(01)93380-5

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Product name:Silane, (1,1-dimethylethyl)dimethyl[(2-methyl-2-cyclopenten-1-yl)oxy]-

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