RHODIUM(I)-CATALYZED ISOMERIZATION OF SILOXYCYCLOPROPANES LEADING TO ENOL SILYL ETHERS AND ALLYL SILYL ETHERS

DOI: 10.1016/S0040-4039(01)93380-5

Source and publish data:

Tetrahedron Letters p. 6887 - 6890 (1989)

Update date:2022-09-26

Topics:

Authors:

Ikura, Kiyoshi

Ryu, Ilhyong

Ogawa, Akiya

Kambe, Nobuaki

Sonoda, Noboru

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)93380-5

The isomerization of siloxycyclopropanes to enol silyl ethers and allyl silyl ethers was accomplished by using 2 as a catalyst.Regiochemistry with respect to the newly formed double bond of the product was highly dependent on the substitution pattern of cyclopropane ring.

Full text of DOI:10.1016/S0040-4039(01)93380-5

Products guided by the article

Product name:Silane, (1,1-dimethylethyl)dimethyl[(2-methyl-2-cyclopenten-1-yl)oxy]-

Cas No:118463-71-1

R&D Labs maybe for 118463-71-1

TLS PHARMACEUTICAL CO.,LTD

Contact:0833-5590788/5590338/5590055

Address:Victory in the town of Red Star Village,Mount Emei City,industrial concentration area storage processing logistics parkpark
Xian Changyue Biological Technology Co., Ltd.

website:https://www.xachangyue.com/

Contact:+86-029-88211911

Address:Keji Road NO.70
Anhui Qingyun Pharmaceutical and Chemical Co.,Ltd

Contact:+86-551-63633067

Address:Shuangfeng Road Hefei Anhui
Shijiazhuang Haotian Chemical Co., Ltd.

Contact:86-311-85044374

Address:293 Donggang Road
Shanghai Mio Chemical Co., Ltd

Contact:0086 21- 64401188-622

Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China

Relevant to this article

Ni(0)-catalyzed 1,4-selective diboration of conjugated dienes

Doi:10.1021/ol101797f
(2010)
Noncalcemic, antiproliferative, transcriptionally active, 24-fluorinated hybrid analogues of the hormone 1α,25-dihydroxyvitamin D₃. Synthesis and preliminary biological evaluation

Doi:10.1021/jm980031t
(1998)
Geminal Alkylations: Substitutions of Allyl Sulfones. Regiocontrol via Molybdenum Catalysis

Doi:10.1021/jo00291a001
(1990)
One-pot synthesis of 2,4,5-trisubstituted 1,2,3-triazoles through the cascade reactions of acid chlorides, terminal acetylenes, sodium azide and aryl halides

Doi:10.1039/c3nj40912k
(2013)
Enantioselective synthesis of 5-trifluoromethyl-2-isoxazolines and their N-oxides by [hydroxy(tosyloxy)iodo]benzene-mediated oxidative N-O coupling

Doi:10.1002/ejoc.201301096
(2013)
Optically active cyclopropanols from the enzymatic resolution of dimethyl α-alkylsuccinates. Synthesis of chiral 2-vinylcyclobutanones and cyclohexenones.

Doi:10.1016/S0040-4039(00)96592-4
(1987)

Article Doi