Etude de la reaction de germyllithiums sur la di-t-butyl-3,5 orthoquinone: mise en evidence d'un mecanisme par transfert monoelectronique

DOI: 10.1016/0022-328X(90)85239-U

Source and publish data:

Journal of Organometallic Chemistry p. 147 - 156 (1990)

Update date:2022-08-02

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Authors:

Riviere, P.

Castel, A.

Ko, Y. H.

Desor, D.

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Article abstract of DOI:10.1016/0022-328X(90)85239-U

Reactions between organogermyllithiums R3GeLi and 3,5-di-t-butylorthoquinone mainly give digermanes but also O-germylcatechol and germadioxolanes.It appears that these reactions start after an initial single electron transfer (SET) which is supported by a

Full text of DOI:10.1016/0022-328X(90)85239-U

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