Journal of the American Chemical Society p. 12050 - 12051 (2009)
Update date:2022-08-04
Topics:
Guimond, Nicolas
Fagnou, Keith
(Chemical Equation Presented) A general rhodium-catalyzed oxidative coupling reaction between internal alkynes and aryl aldimines is described. This process affords 3,4-disubstituted isoquinolines in good yield and high regioselectivity. Preliminary mechanistic studies suggest that the C-N bond formation arises from the reductive elimination of a rhodium(III) species.
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