SYNTHESIS OF DIHYDROPALLESCENSIN D VIA MANGANESE(III) MEDIATED CYCLIZATION OF AN OLEFINIC β-KETO ESTER

DOI: 10.1016/S0040-4039(00)94333-8

Source and publish data:

Tetrahedron Letters p. 59 - 62 (1990)

Update date:2022-08-04

Topics:

Authors:

White, James D.

Somers, Todd C.

Yager, Kraig M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)94333-8

Free radical oxidative cyclization of keto ester 5 with manganese(III) acetate and copper(II) acetate gave bicyclo<4.3.1>decanone 6 which was transformed into the furanosesquiterpene dihydropallescensin D.

Full text of DOI:10.1016/S0040-4039(00)94333-8

Products guided by the article

Product name:3-oxo-5-(2,6,6-trimethyl-cyclohex-2-enyl)-pentanoic acid methyl ester

Cas No:118672-99-4

R&D Labs maybe for 118672-99-4

ZHEJIANG JIANYE CHEMICAL CO.,LTD.

Contact:86-571-64149273,64149234

Address:No. 48, Fuxi Road, Meicheng Town
Chengdu Green technology Co.,Ltd.

Contact:86-28-82608355

Address:C9 ,Economic Headquarters, Economic Development Zone, Chengdu.
Beijing Mediking Biopharm Co., Ltd.

Contact:+86-10-89753524/81760121/81769521

Address:Hongxianghong Incubator, Beiqijia Town, Changping district, Beijing, China
Taimai Sanluck Pharmaceutical Co.,Ltd

Contact:86-592-7662921

Address:8D,No.186,Huarong Road,Huli,Xiamen,China
Shanghai Bocimed Pharmaceutical Co., Ltd.

website:http://www.bocimed.com

Contact:+86-21-68861632

Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai

Relevant to this article

<2+2>- AND <4+2> CYCLOADDITION REACTIONS OF 1,3-DIAZABUTADIENES WITH DIPHENYLKETENE

Doi:10.1016/S0040-4039(00)82482-X
(1988)
Formation of an unusual product in the reaction of a 1,2,5-thiadiazolidine 1,1-dioxide-derived thioether with sulfuryl chloride

Doi:10.1002/jhet.136
(2009)
A_2Badenosine receptor antagonists: Design, synthesis and biological evaluation of novel xanthine derivatives

Doi:10.1016/j.ejmech.2016.11.007
(2017)
Efficient synthesis and cytotoxic activity of some symmetrical disulfides derived from the quinolin-4(1H)-one skeleton ww

Doi:10.1002/ejoc.200900428
(2009)
Efficient fluoride-mediated synthesis of 5-amino-substituted isothiazoles

Doi:10.1055/s-0029-1216844
(2009)
Synthesis of novel 1,2,4-trioxanes and antimalarial evaluation against multidrug-resistant Plasmodium yoelii nigeriensis

Doi:10.1016/j.bmcl.2021.128305
(2021)

Article Doi