SYNTHESIS OF DIHYDROPALLESCENSIN D VIA MANGANESE(III) MEDIATED CYCLIZATION OF AN OLEFINIC β-KETO ESTER

DOI: 10.1016/S0040-4039(00)94333-8

Source and publish data:

Tetrahedron Letters p. 59 - 62 (1990)

Update date:2022-08-04

Topics:

Authors:

White, James D.

Somers, Todd C.

Yager, Kraig M.

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Article abstract of DOI:10.1016/S0040-4039(00)94333-8

Free radical oxidative cyclization of keto ester 5 with manganese(III) acetate and copper(II) acetate gave bicyclo<4.3.1>decanone 6 which was transformed into the furanosesquiterpene dihydropallescensin D.

Full text of DOI:10.1016/S0040-4039(00)94333-8

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