Journal of the Chemical Society. Perkin transactions I p. 2675 - 2680 (1988)
Update date:2022-08-04
Topics: Synthetic studies Total synthesis Chemical Synthesis Experimental Studies Antibiotic
Ogawa, Seiichiro
Miyamoto, Yasunobu
Nose, Taisuke
The first complete synthesis of validamycin B (1a) and validoxylamine B (2a) is reported; coupling of the epoxide (12) and the partially protected derivative (16) of (+)-valienamine, followed by deprotection, gives (1a), which was identified from the 1H n
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