Thermal Reactions of Chromium Aminocarbene Complexes with Alkynes. Synthesis of Bicyclo Lactams

DOI: 10.1021/jo00267a005

Source and publish data:

Journal of Organic Chemistry p. 1241 - 1244 (1989)

Update date:2022-08-05

Topics:

Authors:

Hegedus, Louis S.

Miller, David B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00267a005

((Dimethylamino)methylene)chromium pentacarbonyl underwent thermal reaction with internal alkynes to produce coordinated enaminoketenes.In situ reaction of these with imines produced novel bicyclo<3.1.0> lactams rather than the expected <2 + 2> or <4 + 2>

Full text of DOI:10.1021/jo00267a005

Products guided by the article

Product name:(1R,4S,5S)-3-Benzyl-6-dimethylamino-4-methoxy-1,5-diphenyl-3-aza-bicyclo[3.1.0]hexan-2-one

Cas No:119011-71-1

R&D Labs maybe for 119011-71-1

Hangzhou Yanshan Chemical Co.,Ltd.

Contact:86-571- 87698076

Address:Room 1001, #1 Building, Zhongtian MCC, No.2 Youzhinong, Wenyi West Road, Xihu District, Hangzhou, China
Tianjin SPHINX SCIENTIFIC LAB.

Contact:+86-022-66211289

Address:Tianda high-tech Park. No.80,the 4th Avenue
SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
Shijiazhuang Frontierchem Co., Ltd.

Contact:+86-311-89271196

Address:4-4-202 No.15 Biandian Street,Shijiazhuang
PINGYUAN SIHUAN PHARMACEUTICAL CO., LTD

Contact:+86-531-55696072

Address:#2766,yinxiu Road, Economic Development Zone, Pingyuan Country, Shandong Province, China.

Relevant to this article

Cu-promoted sydnone cycloadditions of alkynes: Scope and mechanism studies

Doi:10.1002/chem.201406118
(2015)
Preparation of New Nitrogen-Bridged Heterocycles. 18. Facile Formations of 3-Arylpyrazolo<1,5-a>pyridines and 1-Arylindolizines

Doi:10.1246/bcsj.61.2055
(1988)
5,15-Bis(di-p-anisylamino)-10,20-diphenylporphyrin: Distant and intense electronic communication between two amine sites

Doi:10.1039/b907413a
(2009)
IMIDAZO<2,1-b>BENZOTHIAZOLES 3: SYNTHESES AND IMMUNOSUPPRESSIVE ACTIVITIVES OF 2-(m-ACYLOXYPHENYL)IMIDAZO<2,1-b>BENZOTHIAZOLES

Doi:10.1016/0223-5234(88)90205-X
(1988)
OXIDATION OF PRIMARY ALIPHATIC AMINES WITH SODIUM PERBORATE

Doi:10.1016/S0040-4039(01)89003-1
(1989)
A general approach to the synthesis of bisindolylmaleimides: Synthesis of staurosporine aglycone

Doi:10.1055/s-1995-4146
(1995)

Article Doi