Thermal Reactions of Chromium Aminocarbene Complexes with Alkynes. Synthesis of Bicyclo Lactams

DOI: 10.1021/jo00267a005

Source and publish data:

Journal of Organic Chemistry p. 1241 - 1244 (1989)

Update date:2022-08-05

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Authors:

Hegedus, Louis S.

Miller, David B.

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Article abstract of DOI:10.1021/jo00267a005

((Dimethylamino)methylene)chromium pentacarbonyl underwent thermal reaction with internal alkynes to produce coordinated enaminoketenes.In situ reaction of these with imines produced novel bicyclo<3.1.0> lactams rather than the expected <2 + 2> or <4 + 2>

Full text of DOI:10.1021/jo00267a005

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