Convenient, enantioselective hydrosilylation of imines in protic media catalyzed by a Zn-trianglamine complex

DOI: 10.1039/c1ob05074e

Source and publish data:

Organic and Biomolecular Chemistry p. 3863 - 3870 (2011)

Update date:2022-07-30

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Authors:

Gajewy, Jadwiga

Gawronski, Jacek

Kwit, Marcin

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Article abstract of DOI:10.1039/c1ob05074e

Chiral hexamine macrocycle derived from trans-1,2-diaminocyclohexane (DACH) in a complex with diethylzinc efficiently catalyzes the asymmetric hydrosilylation of N-phosphorylated aryl-alkyl or aryl-aryl ketimines in protic media with enantiomeric excess o

Full text of DOI:10.1039/c1ob05074e

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