Photochemistry of Cyclopropene Derivatives. 34. Photocycloaddition Reactions of 2-Alkenyl-Substituted Cyclopropenes

DOI: 10.1021/jo00268a026

Source and publish data:

Journal of Organic Chemistry p. 1635 - 1642 (1989)

Update date:2022-08-05

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Authors:

Padwa, Albert

Krumpe, Keith E.

Terry, Lenny W.

Wannamaker, M. Woods

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Article abstract of DOI:10.1021/jo00268a026

The sensitized irradiation of 2-(4-pentenyl)-substituted cyclopropenes produces tricyclo<3.3.0.0^1,3>octanes by means of novel intramolecular <2+2> cycloaddition.In dramatic contrast to the photochemical results, thermolysis affords a product co

Full text of DOI:10.1021/jo00268a026

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