Chemistry Letters p. 811 - 812 (1997)
Update date:2022-07-31
Topics:
Ahiko, Taka-Aki
Ishiyama, Tatsuo
Miyaura, Norio
The cross-coupling reaction of bis(pinacolato)diboron with oxo-2-alkenyl acetates in toluene at 50 °C in the presence of Pd(dba)2/2 AsPh3 (3 mol%) to give allylboronates was followed by the intramolecular allylboration at 100 °C. The sequence provided cyclic homoallyl alcohols in high yields.
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(1988)
