SYNTHESIS OF ENANTIOMERICALLY PURE (10R, 11S)-(+)-JUVENILE HORMONES I AND II

DOI: 10.1016/S0040-4020(01)85826-9

Source and publish data:

Tetrahedron p. 343 - 354 (1988)

Update date:2022-07-31

Topics:

Authors:

Mori, Kenji

Fujiwhara, Mitsuhiko

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Article abstract of DOI:10.1016/S0040-4020(01)85826-9

Enantiomerically pure (+)-juvenile hormone I18JH=JH I> and (+)-juvenile hormone II < methyl(2E,6E,10R,11S)-10,11-epoxy-3,7,11-trimethyl-2,6-tridecadienoate; C₁₇ JH=JH II> were synthesized employing the enantioselective reduction of 2-ethyl-2-methyl-1,3-cyclohexanedione by a yeast (Pichia terricola KI0117) as the key step.

Full text of DOI:10.1016/S0040-4020(01)85826-9

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Product name:(2E,6S,7S)-6,7-isopropylidenedioxy-3,7-dimethyl-2-nonen-1-ol

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