PERFLUORO-ENOLATE CHEMISTRY: FACILE GENERATION AND UNIQUE REACTIVITIES OF METAL F-1-PROPEN-2-OLATES

DOI: 10.1016/S0040-4039(00)80432-3

Source and publish data:

Tetrahedron Letters p. 4119 - 4122 (1988)

Update date:2022-08-04

Topics:

Authors:

Qian, Cheng-Ping

Nakai, Takeshi

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Article abstract of DOI:10.1016/S0040-4039(00)80432-3

Extremely facile methods for generating the metal F-enolates CF3-C(OM)=CF2 (M=Li, Na, K) from CF3CH(OH)CF3 have been developed.Furthermore, the F-enolates are shown to exhibit a unique spectrum of reactivity including the aldol reactivity and the electrop

Full text of DOI:10.1016/S0040-4039(00)80432-3

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