
Tetrahedron Letters p. 2819 - 2822 (1988)
Update date:2022-08-05
Topics:
Bac, Nguyen Van
Langlois, Yves
A double Baeyer-Villiger oxidation of bicyclo<2,2,1> heptane-2,5-dione and a stereocontrolled alkylation of the dianion derived from 4-pentyn-2-ol are the salient features of a new strategy in the stereocontrolled synthesis of the spiroketal moiety of milbemycins.
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