A Remarkable Difference of the Positional Selectivity in Electrophilic Aromatic Substitution of Dibenzofuran between the Classical ?-Complex and Charge-Transfer Mechanisms

DOI: 10.1246/cl.1988.1285

Source and publish data:

Chemistry Letters p. 1285 - 1288 (1988)

Update date:2022-08-03

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Authors:

Keumi, Takashi

Hamanaka, Kozo

Hasegawa, Haruo

Minamide, Naoki

Inoue, Yoshinori

Kitajima, Hidehiko

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Article abstract of DOI:10.1246/cl.1988.1285

Electrophilic nitration of dibenzofuran with nitric acid by a charge-transfer mechanism occurs exclusively at the 3-position and on the other hand, substitution at the 2-position predominates in the acylation, in which a classical ?-complex mechanism is important.

Full text of DOI:10.1246/cl.1988.1285

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