2,3,6,6,-PERDEUTERO-CYCLODEXTRINS POWERFUL NEW FAMILY OF CYCLODEXTRIN FOR NMR SPECTROSCOPY

Article abstract of DOI:10.1016/S0040-4039(00)80524-9

α-, β-, and γ-Cyclodextrins are deuterated at the C2, C3, and C6 positions by the Raney nickel catalyzed H-D exchange reaction in D2O. 1H- and 13C-NMR of these cyclodextrins are highly simplified and, therefore , expected to provide one of strong means for the structure determination of cyclodextrin derivates.