STEREOSPECIFIC 1,4-ADDITION REACTION OF SULFINYLALLYL ANION: SYNTHESIS OF (+/-)-PENTALENOLACTONE E METHYL ESTER

DOI: 10.1016/S0040-4039(00)96755-8

Source and publish data:

Tetrahedron Letters p. 5465 - 5468 (1987)

Update date:2022-07-30

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Authors:

Hua, Duy H.

Coulter, M. Jo

Badejo, Ibraheem

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Article abstract of DOI:10.1016/S0040-4039(00)96755-8

Stereospecific 1,4-Addition reaction of lithiated sulfinylallyl anion and enone 2 provided the corresponding 1,4-γ-adduct, 7.In seven steps, 7 was converted into octahydro-2-methoxy-8,8-dimethylpentalenol<1,6a-c>pyran-5-(6H)-one (9) whose conversion into

Full text of DOI:10.1016/S0040-4039(00)96755-8

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