Synthesis of a C,D-Ring Fragment of Artemisinin

DOI: 10.1021/jo00269a008

Source and publish data:

Journal of Organic Chemistry p. 1789 - 1792 (1989)

Update date:2022-08-05

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Authors:

Avery, Mitchell A.

Jennings-White, Clive

Chong, Wesley K. M.

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Article abstract of DOI:10.1021/jo00269a008

A multistep preparation is described for carboxyvinylsilane 6, which upon reaction with ozone initially gave dioxetane 8 as a transient intermediate in a highly stereoselective manner. Subsequent rearrangement at ambient temperature resulted in cyclizatio

Full text of DOI:10.1021/jo00269a008

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