Journal of Organic Chemistry p. 1789 - 1792 (1989)
Update date:2022-08-05
Topics:
Avery, Mitchell A.
Jennings-White, Clive
Chong, Wesley K. M.
A multistep preparation is described for carboxyvinylsilane 6, which upon reaction with ozone initially gave dioxetane 8 as a transient intermediate in a highly stereoselective manner. Subsequent rearrangement at ambient temperature resulted in cyclizatio
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