Rhodium Acetate Catalyzes the Addition of Carbenoids α- to Ether Oxygens

DOI: 10.1016/S0040-4039(00)99570-4

Source and publish data:

Tetrahedron Letters p. 1749 - 1752 (1989)

Update date:2022-08-03

Topics:

Authors:

Adams, Julian

Poupart, Marc-Andre

Grenier, Louis

Schaller, Chris

Ouimet, Nathalie

Frenette, Richard

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Article abstract of DOI:10.1016/S0040-4039(00)99570-4

Diazo-carbonyl compounds, when catalyzed by rhodium acetate, insert preferentially adjacent to ether oxygens.This phenomenon was exploited to develop a synthesis of 3(2H)-furanones.

Full text of DOI:10.1016/S0040-4039(00)99570-4

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