Pyrrolidine-camphor derivative as an organocatalyst for asymmetic michael additions of α,α-disubstituted aldehydes to β-nitroalkenes: Construction of quaternary carbon-bearing aldehydes under solvent-free conditions

DOI: 10.1002/adsc.200800771

Source and publish data:

Advanced Synthesis and Catalysis p. 1273 - 1278 (2009)

Update date:2022-07-31

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Authors:

Chang, Chihliang

Li, Ssu-Hsien

Reddy, Raju Jannapu

Chen, Kwunmin

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Article abstract of DOI:10.1002/adsc.200800771

A novel pyrrolidine-camphor organocatalyst 3 was designed, synthesized and proven to be an efficient catalyst for the asymmetric Michael reaction. Treatment of α,α-disubstituted aldehydes with β-nitroalkenes in the presence of 20 mol% organocatalyst 3 and

Full text of DOI:10.1002/adsc.200800771

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