Isolation of cationic cyclopentadienyl iron complexes containing phosphinite and formation of metallaphosphineoxide complexes by the Arbuzov-like dealkylation reaction

DOI: 10.1016/0022-328X(92)83225-7

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Journal of Organometallic Chemistry p. 145 - 153 (1992)

Update date:2022-08-03

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Authors:

Nakazawa, Hiroshi

Yamaguchi, Masako

Kubo, Kazuyuki

Miyoshi, Katsuhiko

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Article abstract of DOI:10.1016/0022-328X(92)83225-7

Reaction of (η⁵-C5H5)(CO)2FeCl with PPh2(OR) yields an isolable cationic complex <(η⁵-C5H5)(CO)2Fe>Cl (R = Et, Ia; Me, Ib), which reacts with NaOMe to give <(η⁵-C5H5)(CO)Fe(COOMe)> and with PPh2(OR) to

Full text of DOI:10.1016/0022-328X(92)83225-7

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