Tetrahedron p. 4483 - 4494 (1988)
Update date:2022-08-02
Topics:
Barton, Derek H. R.
Finet, Jean-Pierre
Gianotti, Charles
Halley, Frank
The reactivity of BiV reagents towards very hindered phenols with tert.-butyl groups at 2 and 6 under basic conditions has been studied.Unexpected phenylation at the 4-position and, in several cases, replacement of a tert.-butyl group by phenyl have been observed.The mechanism of these unexpected reactions has been discussed.
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