ortho-SELECTIVE METALATION AND ELECTROPHILIC SUBSTITUTION OF BENZYLAMINE DERIVATIVES

DOI: 10.1016/S0040-4039(00)80473-6

Source and publish data:

Tetrahedron Letters p. 4277 - 4280 (1988)

Update date:2022-07-29

Topics:

Authors:

Simig, Gyula

Schlosser, Manfred

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Article abstract of DOI:10.1016/S0040-4039(00)80473-6

N-Pivaloylbenzylamines and derivatives thereof undergo smooth ortho-metalation when treated with two equivalents of an organolithium reagent.Subsequent carboxylation or hydroxylation lead to a variety of new products.

Full text of DOI:10.1016/S0040-4039(00)80473-6

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