Photoinduced C-C Bond Formation from Alkyl Halides catalysed by Luminescent Dinuclear Gold(I) and Copper(I) Complexes

DOI: 10.1039/DT9920003325

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3325 - 3330 (1992)

Update date:2022-08-05

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Authors:

Li, Dan Li, Dan

Che, Chi-Ming

Kwong, Hoi-Lun

Yam, Vivian Wing-Wah

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Article abstract of DOI:10.1039/DT9920003325

The photoluminescent properties of (2+) , (2+) and (2+) have been investigated.Irradiation of a degassed acetonitrile solution of benzyl chloride or 1-bromopentane in the presence of a sacrificial electron donor such as triethylamine and a catalytic amount of (2+) led to the formation of bibenzyl or n-decane.Similar photoreactions with much lower yields of the C-C bond coupling products have also been observed with (2+) and (2+) as catalysts.The mechanism of the photoreaction between alkyl halides and (2+) has been investigated by steady-state photolysis, Stern-Volmer quenching and flash-photolysis studies.

Full text of DOI:10.1039/DT9920003325

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