Model for Diastereomer Differentiation during 1,2-Addition of Chiral (Racemic) Cyclopentenyl Organometallics to Bicyclic Enones Carrying Exocyclic β,γ-Double Bonds

DOI: 10.1021/jo00271a009

Source and publish data:

Journal of Organic Chemistry p. 2278 - 2291 (1989)

Update date:2022-07-29

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Authors:

Paquette, Leo A.

DeRussy, Donald T.

Gallucci, Judith C.

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Article abstract of DOI:10.1021/jo00271a009

The level of diastereoselection operative during 1,2-addition of several chiral 1-cyclopentenyl dichlorocerate reagents to five differently substituted cis-8-methylenebicyclo<4.2.0>octan-2-ones has been evaluated.The extent of intermolecular recognition r

Full text of DOI:10.1021/jo00271a009

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