A highly stereoselective synthesis of (+)-olivin, the aglycon of olivomycin A

DOI: 10.1021/ja00190a036

Source and publish data:

Journal of the American Chemical Society p. 2984 - 2995 (1989)

Update date:2022-07-30

Topics:

Authors:

Roush Roush

Michaelides

Tai Tai

Lesur Lesur

Chong Chong

Harris Harris

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Article abstract of DOI:10.1021/ja00190a036

The first total synthesis of (+)-olivin (1), the naturally occurring enantiomer of the aglycon of olivomycin A, is described. The synthesis is highly stereoselective, featuring the reaction of (γ-methoxyallyl)boronate 21 with chiral aldehyde 17 and the ad

Full text of DOI:10.1021/ja00190a036

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