THE DIRECTED ORTHO METALATION CONNECTION TO ARYL-ARYL CROSS COUPLING. A GENERAL REGIOSPECIFIC SYNTHESIS OF PHENANTHROLS

DOI: 10.1016/S0040-4039(00)80786-8

Source and publish data:

Tetrahedron Letters p. 5459 - 5462 (1988)

Update date:2022-08-05

Topics:

Authors:

Fu, J.-m.

Sharp, M.J.

Snieckus, V.

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Article abstract of DOI:10.1016/S0040-4039(00)80786-8

A general directed metalation-based cross coupling synthesis of phenanthrols 4 has been developed (Scheme 1); reactions of derived triflates and carbamates 10 lead to a variety of substituted phenanthrenes 7 <*> 12 (Scheme 2).

Full text of DOI:10.1016/S0040-4039(00)80786-8

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