Bulletin of the Chemical Society of Japan p. 3779 - 3781 (1988)
Update date:2022-08-05
Topics:
Sone, Tyo
Inoue, Manabu
Sato, Kazuaki
3-Arylthiophenes were prepared from 2,5-dichlorothiophene in two steps. 2,5-Dichlorothiophene reacted regioselective with various aromatic compounds in the presence of AlCl3 under mild conditions to give 4-aryl-2-chlorothiophenes.The latter compounds were easily converted to the corresponding 3-arylthiophenes by catalytic dechloronation in good yields.
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