Total Synthesis of Albolic Acid and Ceroplastol II, 5-8-5-Membered Tricyclic Insect Sesterterpenoids, via a Lactol-Regulated Silyloxy-Cope Rearrangement

DOI: 10.1039/c39880000354

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 354 - 356 (1988)

Update date:2022-08-04

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Authors:

Kato, Nobuo

Kataoka, Hideo

Ohbuchi, Shoji

Tanaka, Shinya

Takeshita, Hitoshi

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Article abstract of DOI:10.1039/c39880000354

Optically active albolic acid and ceroplastol II, 5-8-5-membered tricyclic sesterterpenoids, were stereoselectively synthesised from two C10 synthons (iridoids) via CrCl2-condensation, lactol-regulated silyloxy-Cope rearrangement with a normally disfavour

Full text of DOI:10.1039/c39880000354

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