CONCERNING THE REACTIVITY OF 1,2:3,4-DIEPOXIDES TOWARDS NUCLEOPHILES

DOI: 10.1016/S0040-4039(00)80506-7

Source and publish data:

Tetrahedron Letters p. 4405 - 4406 (1988)

Update date:2022-08-03

Topics:

Authors:

Esser, Thomas

Sequin, Urs

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Article abstract of DOI:10.1016/S0040-4039(00)80506-7

anti-Benzenedioxide reacts with various nucleophiles to give the products resulting from the attack at both epoxy functions.With butyllithium, however, the formation of a product with a central epoxide is observed.This product is not the result of an epoxide migration but rather of the attack of the nucleophile at the double bond.

Full text of DOI:10.1016/S0040-4039(00)80506-7

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