CONCERNING THE REACTIVITY OF 1,2:3,4-DIEPOXIDES TOWARDS NUCLEOPHILES

DOI: 10.1016/S0040-4039(00)80506-7

Source and publish data:

Tetrahedron Letters p. 4405 - 4406 (1988)

Update date:2022-08-03

Topics:

Authors:

Esser, Thomas

Sequin, Urs

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)80506-7

anti-Benzenedioxide reacts with various nucleophiles to give the products resulting from the attack at both epoxy functions.With butyllithium, however, the formation of a product with a central epoxide is observed.This product is not the result of an epoxide migration but rather of the attack of the nucleophile at the double bond.

Full text of DOI:10.1016/S0040-4039(00)80506-7

Products guided by the article

Product name:(1R,2R,3R,6R)-3,6-Di-tert-butyl-cyclohex-4-ene-1,2-diol

Cas No:120494-28-2

R&D Labs maybe for 120494-28-2

Tianjin Te-An Chemtech Co., Ltd.(expird)

Contact:+86-22-65378638

Address:A5-8, No.80 Haiyun Street, TEDA
Hangzhou TJM Chemical Trade Co., Ltd

Contact:86-571-88223276 86-13388481653

Address:2221#,Boyuexuan,1860# Binsheng Road,Binjiang District, Hangzhou CityZhejiang Province, 310051, P. R. China
Wuhan Shengmao Corp

website:http://www.shengmaochem.com

Contact:86-27-82853423, 82819281

Address:Rm 202, A Unit Huaqiao Building No. 2, Lihuangpi Road, Wuhan, China
Beijing Apis Biotechnology Co., Ltd.

Contact:86-010-67856775-8551

Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA
Ji'an Hairui Natural Plant Co. Ltd.

Contact:0796-8105528

Address:Meilin industry park, Qingyuan district Ji'an City, Jiangxi Province

Relevant to this article

Effective synthesis of optically active trifluoromethyldiazirinyl homophenylalanine and aroylalanine derivatives with the Friedel-Crafts reaction in triflic acid

Doi:10.1271/bbb.90027
(2009)
A rapid and efficient Sonogashira protocol and improved synthesis of free fatty acid 1 (FFA1) receptor agonists

Doi:10.1021/jo902533p
(2010)
A SYNTHESIS OF 2- AND 4(5)-(2-PYRIDINYL)IMIDAZOLES BY PALLADIUM-CATALYSED CROSS-COUPLING REACTIONS

Doi:10.1016/S0040-4039(00)80667-X
(1988)
Asymmetric Synthesis of Multifunctionalized 2,3-Benzodiazepines by a One-Pot N-heterocyclic Carbene/Chiral Palladium Sequential Catalysis

Doi:10.1021/acs.joc.9b02693
(2019)
De novo design of a picomolar nonbasic 5-HT_1B receptor antagonist

Doi:10.1021/jm901200t
(2010)
Microwave assisted [RuCl₂(p-cymene)₂]₂ catalyzed regioselective endo-tandem cyclization involving imine and alkyne activation: An approach to benzo[4,5]imidazo[2,1-a]pyridine scaffold

Doi:10.1039/c4ra02581d
(2014)

Article Doi