
Tetrahedron Letters p. 4763 - 4766 (1988)
Update date:2022-09-26
Topics:
Kuroda, Satoru
Sakaguchi, Shin-ichi
Ikegami, Satoru
Hanamoto, Takeshi
Katsuki, Tsutomu
Yamaguchi, Masaru
The stereochemistry of <2,3>Wittig rearrangement of isopropyl <(2E)-1-(ω-benzyloxyalkyl)-2-butenyl>oxyacetates was found to depend on the position of benzyloxy group and the metal ion used, and in some suitable combinations, (syn,E)- or (syn,Z)-product was obtained with high selectivity.
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(1988)