INTRAMOLECULAR HYDROGEN ABSTRACTION. THE USE OF ORGANOSELENIUM REAGENTS FOR THE GENERATION OF ALKOXY RADICALS

DOI: 10.1016/S0040-4039(00)82887-7

Source and publish data:

Tetrahedron Letters p. 5429 - 5432 (1988)

Update date:2022-08-02

Topics:

Authors:

Dorta, R. L.

Francisco, C. G.

Suarez, E.

Freire, R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)82887-7

The alkoxy radical intemediates, produced by photolysis of several hydroxy compounds in the presence of diphenylselenuranes (1) and iodine, undergo intramolecular hydrogen abstraction to afford cyclic ethers in good yield.

Full text of DOI:10.1016/S0040-4039(00)82887-7

Products guided by the article

Product name:diphenylselenium hydroxyacetate

Cas No:120596-72-7

R&D Labs maybe for 120596-72-7

Dongtai Xinyuan Chemical Co., Ltd.

Contact:+86-21-56733000

Address:404F, 99Nong No.117 Zhongtan Rd. Shanghai
ShangHai Original Economy-Trade Develop Co.,Ltd.,

Contact:86-21-68552131

Address:shanghai
Shanghai Bojing Chemical Co., Ltd.

Contact:021-37122233

Address:6F Buildiing 11,No.388,Baifu Road,District Fengxian.Shanghai, China.
jiangsu hualin chemical co.,ltd.

Contact:86-25-87787402

Address:jaingsu,china
Jinzhou Jiutai Pharmaceutical Co.,Ltd

Contact:+86-0416-5179890

Address:No.41, Taianli, Taihe District, Jinzhou, Liaoning

Relevant to this article

Ligandless iron-catalyzed desulfinylative C-C allylation reactions using Grignard reagents and alk-2-enesulfonyl chlorides

Doi:10.1002/ejoc.200900927
(2009)
Cationic hypericin derivatives as novel agents with photobactericidal activity: Synthesis and photodynamic inactivation of propionibacterium acnes

Doi:10.1111/j.1751-1097.2009.00587.x
(2009)
Synthetic and mechanistic studies on tripledecker complexes with bridging 1H-borole ligands

Doi:10.1016/0022-328X(89)87075-5
(1989)
Green approach to the synthesis of polyfunctionalized pyrazolo[4',3':5,6] pyrido[2,3-d]pyrimidines via microwave-assisted multicomponent reactions in water without catalyst

Doi:10.1080/00397910902962860
(2010)
β-peptide conjugates: Syntheses and CD and NMR investigations of β/α-chimeric peptides, of a DPA-β-decapeptide, and of a PEGylated β-heptapeptide

Doi:10.1002/hlca.200900325
(2009)
Palladium-catalyzed [3C + 2C + 2C] cycloaddition of enynylidenecyclopropanes: Efficient construction of fused 5-7-5 tricyclic systems

Doi:10.1039/b919258a
(2010)

Article Doi