INTRAMOLECULAR HYDROGEN ABSTRACTION. THE USE OF ORGANOSELENIUM REAGENTS FOR THE GENERATION OF ALKOXY RADICALS

DOI: 10.1016/S0040-4039(00)82887-7

Source and publish data:

Tetrahedron Letters p. 5429 - 5432 (1988)

Update date:2022-08-02

Topics:

Authors:

Dorta, R. L.

Francisco, C. G.

Suarez, E.

Freire, R.

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Article abstract of DOI:10.1016/S0040-4039(00)82887-7

The alkoxy radical intemediates, produced by photolysis of several hydroxy compounds in the presence of diphenylselenuranes (1) and iodine, undergo intramolecular hydrogen abstraction to afford cyclic ethers in good yield.

Full text of DOI:10.1016/S0040-4039(00)82887-7

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